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The large number of complexes also reduces the accuracy of the higher order constants. 5(NaC10 4 ) 25 KI UQiCHV 20 K 4(HC10 4 ) K red 49D 4 . 76 dis 51Z ? 81 TENTATIVE fe 69N 20 4 . 62 dis 69N 3(Ν ά ,Η010 4 ) 25 KÎ 4 . 66 KNajHClCV 25 Kx 4 . 49 dis KHClOit) 25 Ki 4 . 5 1 fe Values not Recommended because of possible medium effects. 5(HX) 25 Kx 4 . 86 dis Variable anion. 08. 70Be 0 corr 25 Kx 5 . 45 fe Data c o n v e r t e d from 1^ u s i n g Κ 2 (Η + ) 3 . 1 7 . 08. 17. 70Be 7 IK 7C-p 75C DOUBTFUL (Continued) 32 The Data Tables Temp.

I var); 60K (I var, HF neglected); 60Kb (I var). COMMENTS Complexes have not been s u f f i c i e n t l y well c h a r a c t e r i s e d t o permit higher c l a s s i f i c a t i o n . 5 (NaClO^) , T = 25°) i s also a v a i l a b l e (52Y), and in f a i r agreement with the above. 72 H,In,c KNaClOi,) 25 dis Corrected from 20 , using AHj from 74V. 97. 71W K2 2 . 5 5 ; K3 2 . 3 6 ; H,In,c Corrected from 20 using ΔΚ^ from 74V. 13 KNaClCV 25 K2 2 . 5 9 ; K3 2 . 3 5 dis 68Aa KNaClO^) 25 K2 2 . 8 3 ; K3 2 .

Mn2* MANGANESE ( I I ) DOUBTFUL 3(NaClO^) 25 ΔΗχ 1 5 . 0 AMERICIUM ( I I I ) àSl 44 cal Doubtful K2 v a l u e used in c a l c u l a t i o n s . (See PART A ) . 2 BERKELIUM ( I I I ) àSx Bk3+ DOUBTFUL HNaCKV 25 ΔΗχ 2 7 . 2 àSl 60 Temp. Medium IRON ( I I I ) àSy, LHn Fe Method Ref. 5 ASx 1 3 0 ; AS2 1 0 0 ; AS 3 96 T 53K/55P/56C COMMENTS Unpublished d a t a ( Ι = 0 . 5 ( Ν ε £ 1 0 ι , ) , T=25°) i n 55Y (method=T) and 59Sa (method=cal) agreement w i t h t h e above s u g g e s t s " t e n t a t i v e " c l a s s i f i c a t i o n i s r e a s o n a b l e .

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