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By Jack Barrett, Mournir A. Malati

With basics of Inorganic Chemistry, famous lecturers mix their event to offer an introductory textual content for first and moment 12 months undergraduates.

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Govan, J. Indian Chem. E. M. Malin, Inorg. , 12, 1030, (1973). 20. Y. E. Merbach, B. I. Elding, Inorg. , 26, 1759, (1987). 2 1 . , 253, 50, (1997) 3 Substitution Reactions of Octahedral Complexes Introduction The reactivity of octahedral metal complexes has been the subject of a large number of investigations and the results obtained have been the topic of several recent reviews [14]. In spite of the large volume of data, there are few cases where the detailed aspects of the reaction mechanism have been fully established.

2 Effects of ionic strength Reaction Slope = Z 2+ 3+ (A) [ C o ( N H ) B r ] + Hg(II) - » [ C o ( N H ) O H ] + HgBr 3 5 3 2 5 +2 2 S O " + 2I~-> 2 S 0 ~ + I (C) C H 0 C N = N0 ~ + O H " (D) [Cr(urea) ] + H 0 -> [Cr(urea)OH ] + urea (E) H 0 + 2 H + 2Br" -> 2 H 0 + Br (F) [Co(NH ) Br] + O H " - > [ C o ( N H ) O H ] + Br" (G) Fe g 2 5 4 2 2 2 C H OH + N 0 + C 0 ~ 2 2 5 2 3+ 3 3+ 6 2 2 2 2 2 2+ 3 2+ 2+ 5 3 3 + [Co(C 0 ) ] "-> F e 2 4 3 3+ +1 0 -1 + 2 +4 2 (B) 2 + Z A B 5 2 + 3 C 0 ' + Co 2 4 2 + -2 -6 Fig.

Key accounts by a pioneer in the field. G. Wilkins and M. Eigen, Adv. Chem. , 49, 55, (1965). The key original reference to the Eigen-Wilkins mechanism. T. Richens, Perspectives on Bioinorganic Chemistry, ed. W. R. B. Nolan, JAI Press Connecticut, (1993). Richens, The Chemistry of Aqua Ions, Wiley, New York, (1997). U. Bips, H. Elias, M. Hauroder, G. Kleinhans, S. J. Wannowius, Inorg. , 22, 3862(1983). 17. W. R. /. Chem. Soc. (A), 42, (1969). 18. W. Hay and N. Govan, J. Indian Chem. E. M. Malin, Inorg.

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