By D. D. Perrin
Ionisation Constants of Inorganic Acids and Bases in Aqueous resolution, moment variation presents a compilation of tables that summarize appropriate info recorded within the literature as much as the top of 1980 for the ionization constants of inorganic acids and bases in aqueous resolution. This ebook contains references to acidity features for powerful acids and bases, in addition to information about the formation of polynuclear species. this article then explains the main points of every column of the tables, in which column 1 provides the identify of the substance and the damaging logarithm of the ionization consistent and column 2 supplies the temperature of measurements in measure Celsius. This publication offers besides the strategy of size and the literature references which are indexed alphabetically on the finish of the tables. Chemists will locate this publication helpful.
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4 Er(OH)9 ) 02q -log K for 2Er J1- +. 009 M —a. 3(NaClO 4 ) ρΚ χ 25 (Aquo) gr^iumli I I l ^ Q D / Er 3 + 72. 99 (Aquo) §ί§ΐ£§ΪΠΪΜΐ1ίΐϊ]==4§^ ' E s 71. H102 U2 M87 F49 A27 A26 B152 F49 H102 39 Ε_^__&1_¥=____§:=_ά / 79. 5 · Ε__9___&__2Ε°:Ι_==Ι__ά' H 2 P O 3 F % 82. 81 80. 63 EiliQÜ-iQO' 78. 17 77. Fe(CN)fi <1 T( C) 76. 25; extrapolated against 1% For pK in H 2 S 0 4 , see B14 j in water, based on relative strength in CF^COOH "Practical" constants —a pK freezing-point lowering Other measurements: K53 R E3b E OTHER REDOX REDOX E3bg E3bg E3bg E3bg Methods pK^, pK, variation of redox potential with pH ; extrapolated to I_ = 0.
073 for H 2 0 Thermodynamic quantities are derived from the results. 332 46. 596 45. 096 5 25 20 448 44. 10287T + 2 . 6 1 . 69 50. Di^SiiQhyâia=igi/ D "Practical" constant, in D 2 0; I_ = 1(KC1) "Practical" constant; in D 2 0; I. 33 I n D 2 0 ; t a k i n g pK 2 f o r H 2 C0 3 i n H 2 0 a s 1 0 . 3 3 in H for C0 2 in H 2 0 = 6 . 03 for pK in H 2 0) 49. 97 48. 93 4 7 . 290; l_ = 0 In D 2 0; extrapolated from measurements in ϋ-Ο/Η,-,Ο mixtures; Thermodynamic quantities are derived from the results.
17 77. Fe(CN)fi <1 T( C) 76. 25; extrapolated against 1% For pK in H 2 S 0 4 , see B14 j in water, based on relative strength in CF^COOH "Practical" constants —a pK freezing-point lowering Other measurements: K53 R E3b E OTHER REDOX REDOX E3bg E3bg E3bg E3bg Methods pK^, pK, variation of redox potential with pH ; extrapolated to I_ = 0. 005- and Ga(OH) Successive pK values for hydrolysis of Ga(OH) 4 0 . 0 0 4 - 0 . 2 5 M i n Ga 3 + pK for hydrolysis of Ga 3+. 3+ pK f o r h y d r o l y s i s of Ga ; I_ = 0 .