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2 8 1 T. Mukaiyama and M. Imaoka, Chem. , 1978,413. 282 T. Numata, Y. Watanabe, and S. , 1979, 141 1; 1978,4933. 283 Y. Nagao, K. Kaneko, and E. , 1978,4115. 284 J. Lucchetti and A. R. Hebd. Seances Acad. , Ser. C , 1979, 288, 537. D. Gyorgy, J . Nyitrai, K. Lempert, W. Voelter, and H. Horn, Chem. , 1978, 11 1, 1464. 286 G. Chuchani, I. Martin, and D. B. Bigley, Znt. J. Chem. , 1978, 10,649. 287 K. C. Kole, C . Sandorfy, M. T. Fabi, P. R. Olivato, R. Rittner, C . Trufem, H. Viertler, and B. Wladislaw, J.

Lg9 Anodic oxidation of disulphides in the presence of alkenes in MeCN gives P-acetamidoalkyl sulphides:200 - -e- RSSR MeCN RSSR? RSN=&Me R',C =C R' , MeCONHCR',CR',SR Related double-functionalization procedures for alkenes have been established for the preparation of 2-acetoxyalkyl phenyl selenides [ PhSeSePh with Cu(OAc), and A C O H ] , ~P-hydroxyalkyl ~' aryl sulphides [ArSSAr with Pb(OAc), and TFA, for Markownikov 'trans-hydroxysulphenylation'],202 and @-ketoalkyl selenides [PhSeSePh with Br, and ( B U " , S ~ ) , O I .

1 3 3 D. Scholz and D. Eigner, Monacsh. , 1979, 110, 759. -J. Liu, S. P. Lee, and W. H. Chan, Synth. , 1979, 9, 91. Iz3 Organic Compounds of Sulphur, Selenium, and Tellurium 14 chloride + B U ; S ~ S R ' and ~ ~ carboxylic ester + Me,A1SeMe136) give excellent yields of thiolesters and selenolesters, respectively. The latter compounds can also be reached by alkylation of selenocarboxylates. 137 Addition of ArSeBr to ethyl vinyl ether gives the aryl selenide ArSeCH,CHO rather than the selenolester A I - S ~ C O M ~Ketones .

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