Download Peroxide Chemistry: Mechanistic and Preparative Aspects of by Waldemar Adam PDF

By Waldemar Adam

This choice of thirty articles on examine tasks in all parts of peroxide chemistry, i. e. analytical, biochemical, inorganic, natural, organometallic, actual, spectroscopic, and theoretical features, are the results of a multidisciplinary study software funded by means of the Deutsche Forschungsgemeinschaft (DFG). The emphasis used to be to lie at the improvement of environmentally appropriate, selective (chemo-, regio-, diastereo- and enantioselectivity) oxidations. One bankruptcy specializes in commercial functions that have to fulfill either good value and ecological calls for to stay aggressive sooner or later. newest effects at the results of lipid peroxidation in age-dependent illnesses, which variety from Alzheimer and Parkinson issues to diabetes, rheumatic arthritis, atherosclerosis and cardiovascular ailments also are offered.

Chapter 1 Landmarks within the improvement of natural Peroxide Chemistry (pages 1–38): Manfred Schulz
Chapter 1 contemporary Advances in Homogeneous Catalyzed Epoxidations utilizing Hydrogen Peroxide or tert.?Butyl Hydroperoxide (pages 39–59): Thomas Kratz and Werner Zei?
Chapter 2 Photoinduced Electron?Transfer Reactions of Alkenes and Azide Anions within the Presence of Molecular Oxygen: Formation of 1,2?Azidohydroperoxides and Use As Oxygen?Transfer Reagents (pages 60–77): Axel G. Griesbeck, Jorg Steinwascher and Thomas Hundertmark
Chapter three Preparative Use of Peroxidic Oxidants for Oxygen?Transfer Reactions (pages 78–112): Waldemar Adam, Hans?Georg Degen, Aurelia Pastor, Chantu R. Saha?Moller, Simon B. Schambony and Cong?Gui Zhao
Chapter four Organosulfonic and Sulfonimidic Peracids – New Oxidants for Diastereoselective and Enantioselective Oxidations of natural Substrates (pages 113–127): Manfred Schulz and Ralph Kluge
Chapter five Reactive Peroxo Compounds Generated in Situ from Hydrogen Peroxide: Kinetics and Catalytic software in Oxidation methods (pages 128–138): Horst Elias and Stephane Vayssie
Chapter 6 Carbonyl O?Oxides and Dioxiranes – From Laboratory Curiosities to worthwhile Reagents (pages 139–156): okay. Block, W. Kappert, A. Kirschfeld, S. Muthusamy, okay. Schroeder, W. Sander, E. Kraka, C. Sosa and D. Cremer
Chapter 7 Formation of Dioxiranes and Singlet Molecular Oxygen through the Ketone?Catalyzed Decomposition of Peroxycarboxylic Acids (pages 157–176): Andreas Lange and Hans?Dieter Brauer
Chapter 1 Age and Age?Dependent ailments, a outcome of Lipid Peroxidation (pages 177–208): Gerhard Spiteller, Dieter Spiteller, Wolfgang Jira, Uwe Kie?ling, Angela Dudda, Michael Weisser, Stefan Hecht and Caroline Schwarz
Chapter 2 New Peroxycarboxylic Acids through Lipase Catalysis: training and Oxidation homes (pages 209–231): Siegfried Warwel and Mark Rusch gen. Klaas
Chapter three Transition?Metal?Catalyzed Oxyfunctionalization of Catechol and Flavonol Derivatives (pages 232–248): Florian Schweppe, Holger Sirges, Matthias Pascaly, Mark Duda, Cetin Nazikkol, Werner Steinforth and Bernt Krebs
Chapter four Binding and Activation of Dioxygen by means of Biomimetic steel Complexes (pages 249–280): Ernst?G. Jager, Jutta Knaudt, Kerstin Schuhmann and Anka Guba
Chapter five Transition Metal?Catalyzed Stereoselective Synthesis of Functionalized Tetrahydrofurans (pages 281–300): Simone Drees, Marco Greb, Jens Hartung and Philipp Schmidt
Chapter 1 Metallosalen?Catalyzed uneven Oxygen?Transfer response: Dynamics of Salen Ligand Conformation (pages 301–319): Tsutomu Katsuki
Chapter 2 Transition?Metal Catalyzed Epoxidation of Unfunctionalized Alkenes (pages 320–340): Andreas Scheurer, Paul Mosset, Martina Spiegel and Rolf W. Saalfrank
Chapter three Peroxo Complexes of Molybdenum, Tungsten and Rhenium with section move lively Ligands: Catalysts for the Oxidation of Olefins and Aromatics by way of Hydrogen Peroxide and Bistrimethylsilyl Peroxide (pages 341–364): Carsten Jost, Gunter Wahl, Dirk Kleinhenz and Jorg Sundermeyer
Chapter four Kinetic solution through Jacobsen Epoxidation as a simple path to Podophyllotoxin Analoga (pages 365–380): Torsten Linker, Ulrike Engelhardt and Arunkanti Sarkar
Chapter five practise of Optically energetic Hydroperoxides and Their Use for Stereoselective Oxygen move (pages 381–405): Hans?Jurgen Hamann, Eugen Hoft and Jurgen Liebscher
Chapter 6 New Early Transition?Metal Complexes as Homogeneous Catalysts for Olefin Oxidation (pages 406–432): Wolfgang A. Herrmann, Jorg Fridgen and Joachim J. Haider
Chapter 7 Olefin Epoxidation Catalyzed by way of Molybdenum Peroxo Complexes: A Mechanistic examine (pages 433–453): Werner R. Thiel, Michael Barz, Holger Glas and Anna?Katharina Pleier
Chapter eight Oxidation Reactions in Perfluorinated Solvents (pages 454–468): Bodo Betzemeier and Paul Knochel
Chapter nine Transition?Metal Alkoxide?Catalyzed Oxidation of Phenols, Alcohols, and Amines with tert.?Butyl hydroperoxide (pages 469–493): Horst Adam, Karameli Khanbabaee, Karsten Krohn, Jochen Kupke, Hagen Rieger, Klaus Steingrover and Ingeborg Vinke
Chapter 10 Enantioselective Baeyer–Villiger Reactions and Sulfide Oxidations (pages 494–510): Carsten Bolm
Chapter eleven Chiral Pentacoordinated Manganese Complexes As Biomimetic Catalysts for uneven Epoxidations with Hydrogen Peroxide (pages 511–525): Albrecht Berkessel, Thomas Schwenkreis, Matthias Frauen?Kron, Adrian Steinmetz, Norbert Schatz and Jochen Prox
Chapter 12 Photocatalytic Activation of Oxygen via Iron(III)porphyrins (pages 526–541): Horst Hennig and Doritt Luppa
Chapter thirteen Oxidation and Oxygenation of Substituted Arenes with Alkyl Hydroperoxides or Dioxygen/Mediation by means of Schiff?Base Complexes (pages 542–566): Anton Rieker, Stefan Forster and Emerich Eichhorn
Chapter 1 the character of the Transition constructions for Oxygen Atom move from Peroxy Acids, Dioxiranes and Chiral Bis(silyl) Peroxides (pages 567–600): Robert D. Bach
Chapter 2 Mechanistic features of Transition?Metal?Catalyzed Olefin Epoxidation from Density practical reports (pages 601–619): Notker Rosch, Philip Gisdakis, Ilya V. Yudanov and Cristiana Di Valentin
Chapter three Near?UV Photolysis of Singlet Oxygen Generated by way of strength move from fragrant Molecules in Rare?Gas Matrices (pages 620–639): Murthy S. Gudipati, Robert Wagner, Martin Kalb and Andreas Klein
Chapter four Transition?Metal Ion Chemistry of Peroxides within the gasoline section (pages 640–664): Detlef Schroder, Christoph A. Schalley and Helmut Schwarz

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Sharpless, K. B. J. Am. Chem. Soc. 1981, 103, 464±465. d) Sharpless, K. ; Verhoeven, T. R. Aldrichchim. Acta 1979, 12(4), 63±74. a) Jacobsen, E. N. in: Catalytic Asymmetric Synthesis; Ojima, I. ), VCH Press: New York, 1993. b) Katsuki, T. Coord. Chem. Rev. 1992, 92, 1411±1456. ; Berkessel, A. Tetrahedron Lett. 1993, 34, 4785±4788. ; Katsuki, T. Synlett. 1994, 255.

Traube favoured the cyclic form, whilst A. Rieche preferred the linear form. The addition of ozone to alkenes yields ozonides, which C. D. Harries [74] formulated as five membered ring compounds (later called primary ozonides). On the other hand, H. Staudinger postulated that ozone and alkenes react to form four membered ring intermediates (molozonides), which then underwent rearrangement with cleavage of the C±C bond [75] (Scheme A22). 19 1 Landmarks in the Development of Organic Peroxide Chemistry The final product in Staudinger's concept of ozonization was called the isozonide.

Ges. 1934, 67, 633±638. c) SchoÈnberg, A. Ber. dtsch. Chem. Ges. 1936, 69, 532±533. [35] Bladon, P. J. Chem. Soc. 1955, 2176±2190. [36] Schenck, G. O. Angew. Chem. 1957, 69, 579±599. ; Schenck, G. O. Pure Appl. Chem. 1964, 9, 507. [38] a) Schenck, G. ; Ziegler, K. Naturwiss. 1944, 32, 157. b) Schenck, G. ; Kinkel, K. -J. Liebigs Ann. Chem. 1953, 584, 125±155. [39] a) Schenck, G. ; Wirtz, R. Naturwiss. 1953, 40, 581. ; Schenck, G. O. Liebigs Ann. Chem. 1942, 551, 1±79. [40] a) Gollnick, K; Schenck, G.

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