By C.H. Bamford and C.F.H. Tipper (Eds.)
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The resulting profiles were successfully reproduced with the above values of kd, , k , x 2 , and k d - , . Additional amounts of Fz did not appreciably affect the decomposition of HF [ 1141. 5 . 7 kcal mole- over the temperature interval 2800-7500°K by the techniques of infrared emission [ 1, 1171, vacuum ultraviolet absorption , and the laser-beam deflection method . The latter study assumed that a negliglble amount of dissociation occurred in the incubation period with the consequence that all rate coefficients other than kd, could be neglected for the initial rate measurement.