By Quan Li
This publication specializes in the intriguing subject on self-organized natural semiconductors – from fabrics to equipment purposes. It bargains updated and available assurance of self-organized semiconductors for natural chemistry, polymer technological know-how, liquid crystals, fabrics technological know-how, fabric engineering, electric engineering, chemical engineering, optics, optic-electronics, nanotechnology and semiconductors. Chapters hide chemistry, physics, processing, and characterization. The functions contain photovoltaics, light-emitting diodes (LEDs), and transistors.Content:
Chapter 1 Crystal Engineering natural Semiconductors (pages 1–19): Joseph C. Sumrak, Anatoliy N. Sokolov and Leonard R. Macgillivray
Chapter 2 Conjugated Block Copolymers and Cooligomers (pages 21–38): Yongye Liang and Luping Yu
Chapter three Charge?Carrier shipping and Its Modeling in Liquid Crystals (pages 39–81): Jun?Ichi Hanna and Akira Ohno
Chapter four Self?Organized Discotic Liquid Crystals as Novel natural Semiconductors (pages 83–129): Manoj Mathews and Quan Li
Chapter five Self?Organized Semiconducting Smectic Liquid Crystals (pages 131–163): Ji Ma and Quan Li
Chapter 6 Self?Assembling of Carbon Nanotubes (pages 165–193): Liming Dai
Chapter 7 Self?Organized Fullerene?Based natural Semiconductors (pages 195–224): Li?Mei Jin and Quan Li
Chapter eight High?Efficiency natural sunlight Cells utilizing Self?Organized fabrics (pages 225–266): Paul A. Lane
Chapter nine Selective Molecular meeting for Bottom?Up Fabrication of natural Thin?Film Transistors (pages 267–288): Takeo Minari, Masataka Kano and Kazuhito Tsukagoshi
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Extra resources for Self-Organized Organic Semiconductors: From Materials to Device Applications
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Using a series of 1,3-dihydroxybenzenes, or resorcinols, as SCCFs, the approach has been used to successfully enforce π-π stacking between an anthracene and a thiophene within cocrystals of 2(5-iodoresorcinol)·2(9,10-bis(4-pyridylethynyl)anthracene) and 2(5-methylresorcinol)·2(2,5-bis(4-pyridylethynyl)thiophene), respectively. The acene and thiophene were forced into face-to-face stacks with separation Semiconductor Co-Crystal Former (SCCF) Semiconductor Co-Crystal Former (SCCF) Organic Semiconductor Organic Semiconductor Recognition sites Figure 1-14 Scheme of cocrystallization of organic semiconductor and SCCF.
Single-crystal studies on dHPTTP revealed the molecule to exhibit herringbone packing similar to most oligothiophenes (Fig. 1-6). The improvement in mobility was attributed to a decrease in traps in the thin film owing to alkyl-alkyl interactions similar to DH6T . In related work, Bao et al. have synthesized a series of alkyl- and alkoxy-substituted bisphenylbithiophenes (PTTP) and bisphenylterthiophenes (PTTTP) to study side chain effects on mobility. It was discovered that branching in the side chain leads to a decrease in mobility.