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By Wolfgang Kaim

Spectroelectrochemistry (SEC) is a strong but often low-cost approach which yields mechanistic (“-chemistry”), energy-relevant (“-electro-”) in addition to digital constitution details (“spectro-”). the total diversity of the electromagnetic spectrum could be hired, from X-ray absorption to NMR spectroscopies. SEC is utilized in parts corresponding to analytical, fabrics, supramolecular, floor, polymer, natural, organometallic, inorganic and biochemistry. the foundations of the tactic and sensible directions are provided the following via suitable examples and this booklet will entice scientists from all chemical sub-fields who've a uncomplicated figuring out and event in electrochemistry.

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13. 14. 15. 16. 17. 18. 19. 20. 21. 22. Chapter 1 2002, 124, 10894; K. Crowley and J. Cassidy, J. Electroanal. , 2003, 547, 75; L. Kavan, M. Kalbac, M. Zukalova, M. Krause and L. Dunsch, ChemPhysChem, 2004, 5, 274; E. Alessio, S. Daff, M. Elliot, E. Iengo, L. A. Jack, K. G. Macnamara, J. M. Pratt and L. J. Yellowlees, Trends Mol. , 2004, 339. M. Iwaki, G. Yakovlev, J. Hirst, A. Osyczka, P. L. Dutton, D. Marshall and P. R. Rich, Biochemistry, 2005, 44, 4230. W. N. Hansen, R. A. Osteryoung and T. Kuwana, J.

0). 1; [Ru(NH3)6Cl3] ¼ 1 mM; 20 1C. Figure adapted from ref. 20 and used with permission. macrocycle binds iron tightly as both Fe31 and Fe21, and prevents the dissociation of iron. The ideal Nernstian behaviour of myoglobin during spectroelectrochemistry experiments is often used to calibrate a newly constructed experimental setup and to check the proper functioning of electrodes and other associated components. 1 Coupled Chemical Equilibria High-spin iron in a nonheme environment exhibits a significant change in the thermodynamics and kinetics of protein binding on reduction from Fe31 to Fe21.

Odenwald, B. Ludwig, H. Michel and W. Ma¨ntele, Biochemistry, 1998, 37, 7390. 34. F. Baymann, D. E. Robertson, P. L. Dutton and W. Ma¨ntele, Biochemistry, 1999, 38, 13188. 35. A. L. de Lacey, E. C. Hatchikian, A. Volbeda, M. Frey, J. C. FontecillaCamps and V. M. Fernandez, J. Am. Chem. , 1997, 119, 7181. 36. B. Bleijlevens, F. A. Broekhuizen, A. L. Lacey, W. Roseboom, V. M. Fernandez and S. P. J. Albracht, J. Biol. Inorg. , 2004, 9, 743; A. L. de Lacey, V. M. Fernandez, M. Rousset, C. Cavazza and E.

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