By Rudi van Eldik, Kristin Bowman-James
The 59th quantity during this complete and informative sequence. content material: Contents; Preface; bankruptcy 1. Self-Assembled Metallo-Supramolecular structures Incorporating ß-Diketone Motifs as Structural parts; bankruptcy 2. Coordination Polymer Open Frameworks developed of Macrocyclic Complexes; bankruptcy three. Molecular units in response to Metallocyclam Subunits; bankruptcy four. Molecular acceptance of impartial and Charged site visitors utilizing Metallomacrocyclic Hosts; bankruptcy five. Supramolecular Chemistry of Environmentally suitable Anions; bankruptcy 6. function of Cation Complexants within the Synthesis of Alkalides and Electrides. bankruptcy 7. Structure-Activity stories and the layout of artificial Superoxide Dismutase (SOD) Mimetics as TherapeuticsChapter eight. digital Tuning of the Lability of Inert Co(III) and Pt(II) Complexes; Index. summary: The 59th quantity during this finished and informative sequence
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Jpn. 1956, 29, 852–856. Fackler, J. ; Cotton, F. A. Inorg. Chem. 2, 1963 102–106 and references therein. Cotton, F. ; Wilkinson, G. W. ‘‘Advanced Inorganic Chemistry’’; Wiley: New York, 1988. Bullen, G. ; Pauling, P. Inorg. Chem. 1965, 4, 456–462. Padmanabhan, V. M. Proc. Indian Acad. Sci. 1958, 47A, 329–334. Fay, R. ; Girgis, A. ; Klabunde, U. J. Am. Chem. Soc. 1970, 92, 7056–7060. Girgis, A. ; Fay, R. C. J. Am. Chem. Soc. 1970, 92, 7061–7071. Kruger, G. ; Reynhardt, E. C. Acta Crystallogr. B 1974, 30, 822–824.
A) 50 M. P. SUH AND H. R. MOON hydrogen-bonding interactions between the hydroxyl pendants of the macrocycle in a particular layer and the secondary amines of the macrocycle located in the neighboring layers, which results in 3D structures generating 1D channels. The symmetrical binding mode of BTC3À in 5 is induced by the p–p interactions of the included pyridine molecules with the benzene rings of BTC3À anions in the host layers. The effective cavity sizes of 4 and 5 with the consideration of van der ˚ 2, respectively.
A) 1D linear coordination polymer chain constructed of [Ni(L1)]2+ and BDC2À. (b) Schematic diagram showing how 1D linear chains pack to form channels. Dashed lines indicate hydrogen-bonding interactions between 1D chains. 1(1)1), which results in grooves between the macrocycles in the 1D chain. In the crystal structure, three series of 1D coordination polymer chains extend in three different directions (Fig. 2), and they are packed in the form of a double network of threefold braids (28). In other words, two threefold braids of slanting rods are packed with an inversion of the braids when translated in the perpendicular direction.